High-entropy materials (HEMs) are a groundbreaking class of advanced materials characterized by their unique chemical and microstructural complexity. Unlike traditional materials, which are often composed of one or two principal elements, HEMs contain five or more principal elements. These elements can be combined in equal amounts (equimolar composition) or in specific ratios (non-equimolar composition). This ability to fine-tune the composition enables HEMs to achieve a remarkable combination of properties, making them suitable for a wide range of advanced applications.
HEMs include:
High-Entropy Alloys (HEAs): Metallic elements that often form simple phases, such as face-centred cubic (FCC) and base-centred cubic (BCC). Common elements include aluminium (Al), cobalt (Co), chromium (Cr), iron (Fe), nickel (Ni), titanium (Ti), vanadium (V) , and molybdenum (Mo).
High-Entropy Ceramics (HECs): Non-metallic compounds combined to form a single-phase structure. Typical elements include zirconium (Zr), hafnium (Hf), titanium (Ti), niobium (Nb), and tantalum (Ta).
High-Entropy Oxides (HEOs): Complex oxides containing multiple metal elements. Common elements include magnesium (Mg), nickel (Ni), cobalt (Co), copper (Cu), and zinc (Zn).
High-Entropy Carbides/Nitrides: Materials composed of multiple metal carbides or nitrides. Typical elements include tungsten (W)
, titanium (Ti), zirconium (Zr), hafnium (Hf), niobium (Nb), and tantalum (Ta).
Why Are They Special?
The properties of HEMs can vary, but certain compositions exhibit unique characteristics:
Strength and Hardness
HEAs show superior strength and wear resistance compared to traditional materials.
Thermal Stability
Many HEMs maintain performance in extreme temperatures, including HECs and refractory HEAs.
Corrosion Resistance
Some HEMs are highly resistant to corrosion in harsh environments, like seawater, making them suitable for marine applications.
Anti-fouling
Resistance to growth of marine life can be provided extending the life of subsea components. This same property can enhance the life of implant in Orthopaedic applications.
Enhance conductivity
HEMs can provide improvements in conductivity for electrodes in batteries.
Catalysts
Alternative catalysts can be developed, including for hydrogen applications such as electrolysers & fuel cells.